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TotallyMechanistic | Yet another chemistry blog | totallymechanistic.wordpress.com Reviews
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Yet another chemistry blog
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December | 2006 | TotallyMechanistic
https://totallymechanistic.wordpress.com/2006/12
Yet another chemistry blog. Archive for December 2006. Laquo; TotallyMechanistic home page. December 20, 2006. And apologies also if someone’s comment has not appeared in the comments. I noticed that this thing has some kind of a spam filter installed by default. I managed to unspam one of them (sorry Uncle Al. Didn’t mean to silence you) but I’m not quite sure if some comments were lost. December 13, 2006. 8221; This is the first oddities post. December 12, 2006. Was here) know so much about organic che...
Sodium borohydride/iodine reduction | TotallyMechanistic
https://totallymechanistic.wordpress.com/2006/12/11/sodium-borohydrideiodine-reduction
Yet another chemistry blog. Laquo; And so it all began…. There are many ways to reduce amino acids to amino alcohols but my favourite by far is sodium borohydride/iodine combination ( .pdf. Which is not only non-expensive alternative but also convenient compared to, for example, lithium aluminum hydride (see, I don’t like burning labs). Below is how it looks like chemically written:. So, what is actually happening there? This is how I understand it:. Explore posts in the same categories:. Very nice proto...
Neotripterifordin by Corey/Liu | TotallyMechanistic
https://totallymechanistic.wordpress.com/2007/01/05/neotripterifordin-by-coreyliu
Yet another chemistry blog. Laquo; Still alive. Was writing that “the Aldrich catalog ranks #1 on my list of the top desk references of all time”. I agree, it’s a great help when looking for melting/boiling points, densities, etc. However, I have a computer 2 meters from my hood and 1 meter from my desk, so the Sigma-Aldrich website. Is what I mostly use. I also have another nice desk reference. It’s the total synthesis paper of Neotripterifordin by Corey and Liu ( JACS, 1997, 119, 9929-9930. You know, i...
And so it all began… | TotallyMechanistic
https://totallymechanistic.wordpress.com/2006/12/10/and-so-it-all-began
Yet another chemistry blog. And so it all began…. I know what you are thinking: “Seriously, is there really need for a new chemistry blog? 8221; Actually, I don’t know if you are thinking that but at least I was just a few hours ago. I’ve been an avid reader of chemistry blogs for months and now I just felt that I want to have my own. So what will this blog be about? That I don’t know. And what’s with the name? I’m also really interested in reaction mechanisms. I like knowing. Things happen, not just.
Oddity #1 | TotallyMechanistic
https://totallymechanistic.wordpress.com/2006/12/13/oddity-1
Yet another chemistry blog. Laquo; Kharash-Sosnovsky allylic oxidation. I’ve got a new category again. It’s called “Oddities”. I will put there chemical stuff that I find odd/weird/surprising/etc. They probably aren’t odd, weird or surprising to many of you but they are something that made me go “eh… wtf? 8221; This is the first oddities post. 8221; Now pause for a moment and think how you would expect the H NMR (in d-chloroform) of that stuff to look like (you can ignore the Ar protons). I have experien...
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icpmassspectrometry.blogspot.com
ICP Mass Spectrometry: Why can't power plug configurations be universal?
http://icpmassspectrometry.blogspot.com/2006/10/why-cant-power-plug-configurations-be.html
Wednesday, October 18, 2006. Why can't power plug configurations be universal? We have all this excess noise in the lab, mostly from instrumentation, not from chatty n00bie employees. The lab I work in has two icp optical emission spectrometers and one icp mass spectrometer. Each instrument has a chiller. And the mass spec also has a big ole vacuum pump. The power cord from the vacuum pump is also 220V, European, and different than the chiller cord from Europe. Labels: in the lab. A noise box of death is...
Two-headed chemical mayhem!: February 2007
http://chemical-chimera.blogspot.com/2007_02_01_archive.html
Sunday, February 18, 2007. So I thought I might post something chemistry-related - something I haven't done in a while. Below are three papers I have read recently. After reading almost any of Fujita's papers, I always think to myself "wish I would have published that". His work is simple (in theory), which gives it an intangible elegance. Here ( J. Am. Chem. Soc. Another cool paper, also in the field of coordination chemistry, is a recent review by Nitschke ( Acc. Chem. Res. Anyway, the point of this wo...
The Art of Science: Hydrogen-Mediated C-C Bond Formation
http://angew-jacs.blogspot.com/2007/07/hydrogen-mediated-c-c-bond-formation.html
Sunday, 29 July 2007. Hydrogen-Mediated C-C Bond Formation. In the last group meeting I presented Krische. S work on the hydrogen-mediated C-C bond formation. Krische winned the 2007 Presidential Green Chemistry Challenge Awards. For their development of this methodology. In his 2007 JOC perspective. From a mechanistic point of view, the key for the reductive aldol. Coupling reaction, however, an acid additive is necessary. Based on a computational study. Interestingly, in order to probe the role of acid.
The Art of Science: Cascade Reaction
http://angew-jacs.blogspot.com/2007/08/cascade-reaction.html
Saturday, 11 August 2007. What we can do in Asymmetric Organocatalysis except to design catalysts based on the enamine, iminium mechanism or explore the potential of chiral phosphoric acid? The answer might be Cascade Reactions. That is an unexplored field in organocatalysis except some recent papers published by List, Terada and Wang. Early this year, List reported an amazing reaction which combined enamine catalysis, iminium catalysis and Bronsted acid catalysis to form cyclohexylamine.
Two-headed chemical mayhem!: March 2007
http://chemical-chimera.blogspot.com/2007_03_01_archive.html
Saturday, March 10, 2007. Possible answer to Sam's question. One of our loyal blog readers, Sam, wished to know how primary alcohols were iodinated using triphenylphosphine, iodine and imidazole. Here is it, courtesy of petr. In any case have fun in the thursday morning seminars, Samuel! I wish I was there to see a certain first year PhD student write his messy structures (if you can call them that) on the board together with sound effects. Bob Woodward. Would surely be turning in his grave!
icpmassspectrometry.blogspot.com
ICP Mass Spectrometry: Slow down
http://icpmassspectrometry.blogspot.com/2006/07/slow-down.html
Friday, July 21, 2006. It's hard to keep up in the blog world when your trying to move. I mean moving to a different residence. You always forget how much of a pain it is. I've got everything packed up in I-CHEM boxes swiped from work. Well they're not really swiped, they were getting thrown away. Anyways, anyone know how to clean an extraction lens or re-install instrument controlling software without getting a headache? Subscribe to: Post Comments (Atom). Shootin' ions into the vacuum".
icpmassspectrometry.blogspot.com
ICP Mass Spectrometry: The Golden Run
http://icpmassspectrometry.blogspot.com/2006/05/golden-run.html
Thursday, May 25, 2006. Last night's run was what we analytical chemists call a golden run. This means that all the analytes that I needed to analyze for, for each sample, had the yellow highlighter run over them on the cover page of the lab report. The yellow highlighter means that the result is good to go and I don't need to reanalyze. This has only happened one other time in the year I have been running the mass spec. In the lab ,. My site; Minecraft 1.5 Part 1. My site Bukkit Tutorial Series. She bli...
icpmassspectrometry.blogspot.com
ICP Mass Spectrometry: Plasma in the window
http://icpmassspectrometry.blogspot.com/2006/06/plamsa-in-window.html
Sunday, June 25, 2006. Plasma in the window. You know a lot of people play Sudoku and work crossword puzzles to exercise their mind. Any chemists out there ever try to draw out syntheses for natural products or any other molecules to gain extra brain power? Here's a shot of the plasma from the lab. Pick 3 Turbo Player. If you get a chance, check out my site: Pick 3 Turbo Player. I have no idea what pick 3 is. Is this spam? Subscribe to: Post Comments (Atom). Shootin' ions into the vacuum".
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Blog de totallyme1996 - X__ANAiiS__X - Skyrock.com
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totallyme88's blog - <3 mE my sTyLe My lIfE <3 - Skyrock.com
3 mE my sTyLe My lIfE 3. Voila chui de remonde avc un re news bl0og @ @. 07/05/2007 at 12:20 PM. 23/11/2007 at 3:55 PM. MeEeEeEeEeEeEe. o 0. Subscribe to my blog! A=http:/ bricesworld88.skyblog.com]. Don't forget that insults, racism, etc. are forbidden by Skyrock's 'General Terms of Use' and that you can be identified by your IP address (66.160.134.62) if someone makes a complaint. Please enter the sequence of characters in the field below. Posted on Friday, 23 November 2007 at 3:52 PM. Don't forget tha...
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TotallyMechanistic | Yet another chemistry blog
Yet another chemistry blog. Posted January 5, 2007 by totallymechanistic. Was writing that “the Aldrich catalog ranks #1 on my list of the top desk references of all time”. I agree, it’s a great help when looking for melting/boiling points, densities, etc. However, I have a computer 2 meters from my hood and 1 meter from my desk, so the Sigma-Aldrich website. Is what I mostly use. The reactions on that paper are, for example:. Wittig salt preparation/Wittig reaction. I’ve got a new category again&#...
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בית הפקות לסרטי וידאו ואנימציה. עוסקים וחיים שיווק בוידאו באמצעות סרטים וניהול קמפיינים באינטרנט. אנחנו יוצרים תוכן וידאו. ללקוחות פרטיים, מוסדיים ולערוצי הטלוויזיה ואוהבים את מה שעושים. מקצוענות, יצירתיות וניסיון רב, מאפיינים את הצוות של של טוטאלי מדיה. שיווק בוידאו. הוא תחום חי ומתפתח בקצב מהיר, לכן אנחנו בטוטאלי מדיה מתעדכנים ללא הרף בטכנולוגיות חדשניות, וביצירת סגנונות ורעיונות מקוריים. רואים עצמנו מחוייבים לרוץ קדימה כדי להמשיך ולהציע ללקוחותינו הפקות בסטנדרט גבוה. טוטאלי מדיה הוקמה ע י טל הר-ציון.
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